In my environment at work we have a policy that we thin provision all new VMs. We had an issue with a datastore that was running out of space, so I starting looking into it and found that several of the VMs on this datastore were set with thick provisioning on the hard drives.
Get-Datastore | Get-VM | Get-HardDisk | Where {$_.storageformat -eq "Thick" } | Select Parent, Name, CapacityGB, storageformat | FT -AutoSize
This outputs a list of VMs with the storageformat that is set to thick. This enables us to use this list to be able to get a maintenance window to fix these systems.
The biggest problem with this route is having to keep a close eye on the free space on the datastores, as you can easily fill one up without thinking.
-Stuart